On
 Exadata Database Machines - below SMTP configuration parameters can be set via dbmcli or cellcli on Compute and Storage nodes respectively.
- smtpServer
- smtpFrom
- smtpFromAddr
- smtpToAddr
- smtpPort
- smtpUseSSL
- snmpSubscriber
In our environment, we were only required to change the SMTP server, thus everything else was retained as default setting. Though, post updating SMTP relay/server name below error was seen.
DBM-02578: An error was detected in the SMTP configuration: DBM-05503: An error was detected during notification. The text of the associated internal error is: E-mail Address is invalid: 451 5.7.3 STARTTLS is required to send mail    
Compute Nodes:
DBMCLI>alter dbserver smtpFromAddr=’dbmadmin@node01.example.com’
DBMCLI>alter dbserver smtpToAddr=’oracleteam@example.com’
DBMCLI>alter dbserver smtpServer=’newsmtp.example.com’
DBMCLI>alter dbserver smtpUseSSL=TRUE
DBMCLI>alter dbserver validate mail
DBM-02578: An error was detected in the SMTP configuration: DBM-05503: An error was detected during notification. The text of the associated internal error is: E-mail Address is invalid: 451 5.7.3 STARTTLS is required to send mail
I couldn't find any official documentation to enable this, but setting below worked like a charm!
DBMCLI>alter dbserver smtpStartTLS=TRUE
DBMCLI>alter dbserver validate mail
Works!
 
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